This episode discusses the controversy over the carbocation in organic chemistry in the 1950s, and experiments done to resolve the argument through the early 1960s, using superacids, especially in research by George Olah, William von Eggers Doering, and Lawrence H. Knox. We mention the main proponent, Saul Winstein and the main nay-sayer, Herbert Brown. We also take you through the basics of what a superacid is--and is not--and how dangerous superacids can be in the laboratory. Supporters of the podcast at Patreon can download a supplemental sheet with molecular structures. <a rel="payment" href="https://www.patreon.com/thehistoryofchemistry">Support the Show.</a><ul> <li>Support my podcast at <a href='https://www.patreon.com/thehistoryofchemistry'>https://www.patreon.com/thehistoryofchemistry</a> </li> <li>Tell me how your life relates to chemistry! E-mail me at steve@historyofchem.com</li> <li>Get my book, O Mg! How Chemistry Came to Be, from World Scientific Publishing, <a href='https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook'>https://www.worldscientific.com/worldscibooks/10.1142/12670#t=aboutBook</a> </li> </ul>

62: It is Rocket Science

Chemistry is everywhere, and involves everything. But how did chemistry get to be what it is? I'm Steve Cohen, a chemist and writer, bringing you The History of Chemistry. This podcast explores the development of chemistry from prehistoric times to the present, including the people and societies who made chemistry what it is today. The History of Chemistry is for you, whether you hated chemistry in high school, or got a PhD in inorganic chemistry. We'll explore how chemistry affected art, music, language, politics and vice-versa. Whether it's ancient Greek philosophers, medieval alchemists, or modern laboratory apparatus, it's all here. Don't forget to support my series at https://www.patreon.com/thehistoryofchemistry !